Product ID:LACQUER TT-L-20A RED 31136
MSDS Date:08/05/1992
FSC:8010
NIIN:00-166-3151
MSDS Number: BPTWG

CRAWFORD LABS, INC

4165 S EMERALD AVE
CHICAGO, IL 60609
US

Emergency Phone: 312-433-1307

Info Phone: 312-376-7132

Cage: 5V430

CRAWFORD LABORATORIES, INC

CHICAGO, IL 60609 US

Telephone: 312-376-7132

Cage: 5V430

TOLUENE (SARA III) (VAPOR PRESSURE 36 MM HG) (THE ABOVE

CAS: 108-88-3

RTECS: XS5250000

Fraction By Weight: 20-50%

OSHA PEL 200 PPM/150 STEL

ACGIH TLV: 50 PPM; 9293

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

ISOPROPANOL (SARA III) (VAPOR PRESSURE 33 MM HG)

CAS: 67-63-0

RTECS: NT8050000

Fraction By Weight: 5-20%

OSHA PEL 400 PPM/500 PPM STEL

ACGIH TLV: 400 PPM/500 PPM STEL

ISOBUTYL ISOBUTYRATE (VAPOR PRESSURE 3.2 MM HG)

CAS: 97-85-8

RTECS: NQ5250000

Fraction By Weight: 5-20%

METHYL ETHYL KETONE (SARA III) (VAPOR PRESSURE 71.2 MM HG)

CAS: 78-93-3

RTECS: EL6475000

Fraction By Weight: 1-5%

OSHA PEL 100 PPM

ACGIH TLV: 200 PPM

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

METHYL ISOBUTYL KETONE (SARA III) (VAPOR PRESSURE 15 MM

CAS: 108-10-1

RTECS: SA9275000

Fraction By Weight: 5-20%

OSHA PEL 100 PPM/75 STEL

ACGIH TLV: 50 PPM/75 STEL; 9293

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

CRYSTALLINE SILICA (IARC DETERMINED THERE IS LIMITED

CAS: 14464-46-1

RTECS: VV7325000

Fraction By Weight: 5-20%

OSHA PEL SEE TABLE Z3

ACGIH TLV: 0.05 MG/M3 RDUST9293

MAGNESIUM SILICATE HYDRATE (CONTAINS CRYSTALLINE SILICA AT

CAS: 14807-96-6

RTECS: WW2710000

Fraction By Weight: 1-5%

ACGIH TLV: 2 MG/M3

LEAD (SARA III) WARNING - DRIED FILM OF THIS PAINT MAY BE

CAS: 7439-92-1

RTECS: OF7525000

Fraction By Weight: 1-5%

OSHA PEL 0.05 MG/M3

ACGIH TLV: 0.15 MG/M3

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

CHROMATE (AS CR+6)

CAS: 1333-82-0

RTECS: GB6650000

Fraction By Weight: <1%

OSHA PEL .1 MG/M3

ACGIH TLV: .05 MG/M3

ANTIMONY (+3) OXIDE (LONG TERM INHALATION STUDIES INDICATE

CAS: 1309-64-4

RTECS: CC5650000

Fraction By Weight: <1%

OSHA PEL 0.5 MG/M3

ACGIH TLV: 0.5 MG/M3

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

RED PIGMENT 48 (PRODUCT CONTAINS 14 % MAGANESE CAS N

CAS: 5280-66-0

Fraction By Weight: 5-20%

ACGIH TLV: 5 MG/M3

DIOCTYL PHTHALATE (SARA III) (POTENTIALLY CARCINOGENIC

CAS: 117-81-7

RTECS: TI0350000

Fraction By Weight: 1-5%

ACGIH TLV: 5 MG/M3

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

NITROCELLULOSE

CAS: 9004-70-0

RTECS: FJ6000000

Fraction By Weight: 5-20%

610 GPL

RTECS: 9999999VO

Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES
Health Hazards Acute and Chronic:ACUTE TOXICITY, RESULTING IN HEADACHE,
DIZZINESS, NAUSEA, LOSS OF CONSCIOUSNESS. SEVERE EYE IRRITATION,
PERMANENT DAMAGE. IRRITATED MUCOUS MEMBRANES. VOMITING DUE TO
INGESTION. DEFATTING AND DRYING OF THE SKIN. SENSITIZATION AFTER
REPEATEDCONTACT. IF INGESTED, LIQUID OR MIST MAY CAUSE MODERATE
GASTRIC SYSTEMIC UPSET
Explanation of Carcinogenicity:IARC LISTS CRYSTALLINE SILICA,ANTIMONY
OXIDE AND DIOCTYL PHTHALATE AS CARCINOGENS.
Effects of Overexposure:INCLUDING NAUSEA AND ABDOMINAL CRAMPS. CONTAINS
LEAD, DO NOT APPLY TO TOYS, CHILDRENS ARTICLES, FURNITURE OR
INTERIOR DWELLINGS.

First Aid:EYE: FLUSH W/WATER 15 MIN, LIFT EYELID. GET MED AID. INHAL:
MOVE TO FRESH AIR, GIVE OXYGEN IF BREATHING DIFFICULT. GIVE ARTIF
RESP, IF NOT BREATHING. GET MED AID. KEEP WARM, COMFORTABLE. NEVER
GIVE UN CONSCIOUS PERSON LIQ. INGEST: CALL DR IMMED. INDUCE VOMIT
ON DR'S INSTRUCTS. IF VOMIT OCCURS, KEEP HEAD BELOW HIP TO PREVENT
ASPIRATION INTO LUNG. SKIN: FLUSH W/WATER, REMOVING CONTAM CLOTH &
SHOES.

Flash Point Method:SCC
Flash Point:27.0F,-2.8C
Lower Limits:0.28
Extinguishing Media:FOAM, CO2, DRY CHEMICAL
Fire Fighting Procedures:USE WATER TO KEEP EXPOSED CONTAINERS COOL, &
KEEP FLAMMABLE STRUCTURES WET. DONT ENTER FIRE AREA W/OUT PROPER
PROTECTION BECAUSE HZD DECOMP PROD MAY BE PRESENT.
Unusual Fire/Explosion Hazard:WATER PRESSURE MAY SPREAD A FLAMMABLE
LIQUID FIRE. SEALED CONTAINERS MAY EXPLODE IF OVERHEATED.

Spill Release Procedures:WARNING - FLAMMABLE. ELIMINATE ALL IGNITION
SOURCES. HANDLING EQUIPMENT MUST BE GROUNDED TO PREVENT SPARKING.
SOAK UP WITH AN ABSORBENT AND PLACE IN NON-LEAKING CONTAINERS. SEAL
TIGHTLY FOR PROPER DIS POSAL.
Neutralizing Agent:N/K WASH W/SOAP & WATR. DONT REUSE CONTAM
CLOTHING/SHOES. GET MED AID.

Handling and Storage Precautions:FLAMMABLE.KNOW DOT REGS BEFORE
TRANSPORT.HOT ORGANIC CHEM VAPOR/MIST SUSCEPTABLE TO SUDDEN COMBUST
WHEN MIXED W/AIR. IGNIT MAY OCCUR AT TEMPS BELOW#
Other Precautions:#AUTOIGNIT/IGNIT.IGNIT TEMPS DECREASE W/INCREASE
VAPOR VOL,VAPOR/AIR CONTACT TIME,INFLUENCED BY PRESSURE
CHANGE.IGNIT MAY OCCUR AT TYPCL ELEVATED TEMP PROCESS COND,ESPCLLY
IN PROCESS OPERATING UNDER V ACUUM IF SUDDEN INGRESS OF
AIR/OUTSIDE##

Respiratory Protection:PROVIDE ADEQUATE VENT TO MAINTAIN VAPOR CONC
BELOW ESTABLISHED TLV. IN MORE CONFINED AREA A NIOSH/MSHA RSPRTR
EQUIPPED WITH ORGANIC VAPOR CARTRIDGE SHOULD BE WORN.
Ventilation:MUST PROVIDE ADEQUATE VENTILATION TO MAINTAIN VAPOR CONC
BELOW ESTABLISHED TLV.
Protective Gloves:USE RUBBER GLOVES
Eye Protection:SAFETY GOGGLES AND/OR FACE SHIELD
Other Protective Equipment:HAVE EYE BATH AND SAFETY SHOWER AVAILABLE.
Supplemental Safety and Health
## PROCESS EQUIP OPERATING UNDER ELEVATED PRESSURE IF SUDDEN ESCAPE OF
VAPORS/MISTS TO ATMOSPHERE OCCURS. ANY PROPOSED USE OF THIS PRODUCT
IN ELEVATED TEMPERATURE PROCESSES SHOULD BE THOROUGHLY EVALUA TED
TO ASSURE THAT SAFE OPERATING CONDITIONS ARE ESTABLISHED AND
MAINTAINED.

HCC:F2
Boiling Pt:B.P. Text:174 TO 446F
Vapor Density:> AIR
Spec Gravity:1.09
Viscosity:70 KU
Evaporation Rate & Reference:1.44 X N-BUTYL ACETATE
Solubility in Water:SLIGHT
Appearance and Odor:RED LIQUID, SOLVENT ODODR
Percent Volatiles by Volume:71.9
Corrosion Rate:NOT CORR

Stability Indicator/Materials to Avoid:YES
MAY BE INCOMPATIBLE WITH OXIDIZING AGENTS AND STRONG ALKALIES.
Stability Condition to Avoid:AVOID HEAT, SPARKS, OPEN FLAMES, AND
INCOMPATIBILITIES BELOW.
Hazardous Decomposition Products:INCOMPLETE COMBUSTION FOR PRODUCTS
LIKE THIS MAY GENERATE HIGHLY POISONOUS CARBON MONOXIDE AND OTHER
TOXIC GASES.
Conditions to Avoid Polymerization:AVOID HEAT, SPARKS, OPEN FLAMES, AND
INCOMPATIBILITIES ABOVE.

Waste Disposal Methods:DISPOSAL MUST BE IN ACCORDANCE WITH CURRENT
LOCAL, STATE, AND FEDERAL REGULATIONS. CONTACT AN APPROVED DISPOSAL
FACILITY.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.